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    Thirty years of fast-tracking chemical reactions with microwaves aspirin case

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    Trabalho apresentado em evento
    Date
    2017
    Author
    Jermolovicius, Luiz Alberto
    Pouzada, Eduardo V. S.
    Stefanelli, A.R.
    Nascimento, Renata Borges do
    Castro, Edmilson Renato de
    Senise, José Thomaz
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    Abstract
    This paper compares empirical chemical kinetic equations for salicylic acid acylation obtained under 2.45 GHz electromagnetic radiation with conventional electric heating. Results show changes in the activation energy value and in reactions orders, which indicate an alteration of the reaction mechanism. This mechanism alteration is accepted as the cause for microwave enhancement of this reaction. A new concept of microwave irradiated chemical reactor used in these experiments is described. © 2017 IEEE.
    1. Aspirin synthesis
    2. Chemical kinetics equation
    3. Microwave chemistry
    4. Reactor for microwave enhanced synthesis
    5. Activation energy
    6. Electromagnetic waves
    7. Integral equations
    8. Kinetic theory
    9. Optoelectronic devices
    10. Salicylic acid
    11. Chemical kinetic equations
    12. Fast-Tracking
    13. Microwave chemistry
    14. Microwave enhancement
    15. Microwave-enhanced synthesis
    16. Reaction mechanism
    17. Microwaves
    URI
    https://www.scopus.com/inward/record.uri?eid=2-s2.0-85043463147&doi=10.1109%2fIMOC.2017.8121150&partnerID=40&md5=6fb15939467887ffd574ad3b581a5171
    https://repositorio.maua.br/handle/MAUA/819
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