Thirty years of fast-tracking chemical reactions with microwaves aspirin case
Abstract
This paper compares empirical chemical kinetic equations for salicylic acid acylation obtained under 2.45 GHz electromagnetic radiation with conventional electric heating. Results show changes in the activation energy value and in reactions orders, which indicate an alteration of the reaction mechanism. This mechanism alteration is accepted as the cause for microwave enhancement of this reaction. A new concept of microwave irradiated chemical reactor used in these experiments is described. © 2017 IEEE.
- Aspirin synthesis
- Chemical kinetics equation
- Microwave chemistry
- Reactor for microwave enhanced synthesis
- Activation energy
- Electromagnetic waves
- Integral equations
- Kinetic theory
- Optoelectronic devices
- Salicylic acid
- Chemical kinetic equations
- Fast-Tracking
- Microwave chemistry
- Microwave enhancement
- Microwave-enhanced synthesis
- Reaction mechanism
- Microwaves
URI
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85043463147&doi=10.1109%2fIMOC.2017.8121150&partnerID=40&md5=6fb15939467887ffd574ad3b581a5171https://repositorio.maua.br/handle/MAUA/819
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